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Mathematical model of heat capacity of condensed substances using average molar volumes of elements

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Date

2023-11

Authors

Kozub, Pavlo
Miroshnichenko, Nataliia
Kozub, Svetlana
Syrova, Ganna

Journal Title

Journal ISSN

Volume Title

Publisher

Perfect Publishing

Abstract

The mathematical dependence of the isobaric heat capacity on the average molar volumes of chemical compounds and the number of atoms in the formula unit for the condensed state in the widest possible temperature range is obtained. It is established that, in contrast to entropy, the influence of the size of the compound (number of atoms of the formula unit) is less than the influence of the average molar volume. It is shown that the proposed mathematical model allows calculating the entropy of a compound with an average accuracy of 8 J/(mol К).

Description

Keywords

average molar volume, isobaric heat capacity, temperature dependence, 2023а

Citation

Mathematical model of heat capacity of condensed substances using average molar volumes of elements / P. Kozub, N. Miroshnichenko, S. Kozub, G. Syrova // Innovative development of science, technology and education : Proceedings of the 2nd International scientific and practical conference, Vancouver, Canada, 16─18 November, 2023 / Perfect Publishing. – Vancouver : Perfect Publishing, 2023. – P. 203–208.